Rh2(1,3-diisocyanopropane)42+ [triplet]

excited state quenched by 1,4-Diazabicyclo[2.2.2]octane
Milder, S.J.; Goldbeck, R.A.; Kliger, D.S.; Gray, H.B.
J. Am. Chem. Soc. 102: 6761-4 (1980)

Rh2(1,3-diisocyanopropane)42+ [triplet] quenched by 1,4-Diazabicyclo[2.2.2]octane
Solvent : Acetonitrile, 21ºC

kq = 3.3 x 106(L mol–1 s–1)

Mechanism: reductive electron transfer
Experimental methods: laser flash, luminescence, single shot signal
Lifetime in the absence of quencher, air free = 8.5 micro sec.

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