Rh2(1,3-diisocyanopropane)42+ [singlet]

excited state quenched by Diethyl fumarate
Fukuzumi, S.; Nishizawa, N.; Tanaka, T.
Bull. Chem. Soc. Jpn. 56: 709-14 (1983)

Rh2(1,3-diisocyanopropane)42+ [singlet] quenched by Diethyl fumarate
Solvent : Acetonitrile

kq = 6.8 x 109(L mol–1 s–1)

Mechanism: oxidative electron transfer
Experimental methods: steady state irradiation, luminescence
Lifetime in the absence of quencher, air free = 0.0013 micro sec. (80A270)
This value also reported in 83C021

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