Pt(CN)42–

excited state quenched by Ni(CN)42–
Schindler, J.W.; Adamson, A.W.
Inorg. Chem. 21: 4236-40 (1982)

Pt(CN)42– quenched by Ni(CN)42– at conc. 0.046 mol L–1
Solvent : H2O, 22.5ºC

kq = 1.3 x 108(L mol–1 s–1)


Experimental methods: steady state irradiation, luminescence
Lifetime in the absence of quencher, air free = 0.64 micro sec. (laser flash, luminescence, single shot signal)
Comments: [S] = 0.40 mol/L, as K+ salt; forms oligomers

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