Pd(2,3,7,8,12,13,17,18-octaethylporphyrin)

excited state quenched by MV2+
Young, R.C.; Meyer, T.J.; Whitten, D.G.
J. Am. Chem. Soc. 98: 286-7 (1976)

Pd(2,3,7,8,12,13,17,18-octaethylporphyrin) quenched by MV2+
Solvent : iso-Butyronitrile

kq = 1.5 x 109(L mol–1 s–1)

Mechanism: oxidative electron transfer
Experimental methods: steady state irradiation, luminescence
Lifetime in the absence of quencher, air free = 360 micro sec. (conventional flash, luminescence, single shot signal)

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