Os(bpy)32+

excited state quenched by Ru(CN)64–
Juris, A.; Manfrin, M.F.; Maestri, M.; Serpone, N.
Inorg. Chem. 17: 2258-61 (1978)

Os(bpy)32+ quenched by Ru(CN)64–
Solvent : H2O, 0.5 mol/L NaCl, ~20ºC

kq = 1.3 x 108(L mol–1 s–1)

Mechanism: reductive electron transfer
Experimental methods: steady state irradiation, luminescence
Lifetime in the absence of quencher, air saturated = 0.021 micro sec. (spark lamp, luminescence, single photon counting)

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