Mo6Cl142–

excited state quenched by Tetracyanoethene
Maverick, A.W.; Najdzionek, J.S.; MacKenzie, D.; Nocera, D.G.; Gray, H.B.
J. Am. Chem. Soc. 105: 1878-82 (1983)

Mo6Cl142– quenched by Tetracyanoethene
Solvent : Acetonitrile, 27ºC

kq = 2.5 x 109(L mol–1 s–1)

Mechanism: oxidative electron transfer
Experimental methods: steady state irradiation, luminescence
Lifetime in the absence of quencher, air free = 180 micro sec. (laser flash, luminescence, single shot signal)

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