Mo6Cl142–

excited state quenched by PW12O403–
Maverick, A.W.; Najdzionek, J.S.; MacKenzie, D.; Nocera, D.G.; Gray, H.B.
J. Am. Chem. Soc. 105: 1878-82 (1983)

Mo6Cl142– quenched by PW12O403–
Solvent : H2O, 2 mol/L HCl, 27ºC

kq = ~7 x 108(L mol–1 s–1)

Mechanism: oxidative electron transfer
Experimental methods: steady state irradiation, luminescence
Lifetime in the absence of quencher, air free = 20 micro sec. (81E076)
Comments: tau0 in 6 mol/L HCl and 6 mol/L LiCl

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