Mg(etioporphyrin I) [singlet]

excited state quenched by cis-4-Nitrostilbene
Lopp, I.G.; Hendren, R.W.; Wildes, P.D.; Whitten, D.G.
J. Am. Chem. Soc. 92: 6440-7 (1970)

Mg(etioporphyrin I) [singlet] quenched by cis-4-Nitrostilbene
Solvent : Benzene

kq = 1.1 x 1010(L mol–1 s–1)

Mechanism: exciplex formation
Experimental methods: steady state irradiation, luminescence
Lifetime in the absence of quencher, air free = 0.012 micro sec. (laser flash, luminescence, single shot signal)
Comments: nonlinear Stern-Volmer plot at high [Q]

back...