Mg(tetramethoxyphthalocyanine)

excited state quenched by MV2+

Ohtani, H.; Kobayashi, T.; Tanno, T.; Yamada, A.; Woehrle, D.; Ohno, T.
Photochem. Photobiol. 44: 125-9 (1986)

Mg(tetramethoxyphthalocyanine) quenched by MV2+
Solvent : DMF/H2O (9/1)

kq = ~7 x 107(L mol–1 s–1)

Mechanism: oxidative electron transfer
Experimental methods: laser flash, absorption, multiple shot with signal averaging
Lifetime in the absence of quencher, unknown oxygen content = ~240 micro sec.
Comments: S possibly a mixture of isomers


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