Cu(2,9-Me2phen)2+

excited state quenched by Hexachlorobenzene
Blaskie, M.W.; McMillin, D.R.
Inorg. Chem. 19: 3519-22 (1980)

Cu(2,9-Me2phen)2+ quenched by Hexachlorobenzene
Solvent : CH2Cl2, 25ºC

kq < 1 x 109(L mol–1 s–1)

Mechanism: oxidative electron transfer
Experimental methods: steady state irradiation, luminescence
Lifetime in the absence of quencher, unknown oxygen content = 0.054 micro sec. (laser flash, luminescence, single shot signal)

back...