Cu(MePh2P)3Cl

excited state quenched by Norbornadiene
Fife, D.J.; Moore, W.M.; Morse, K.W.
J. Am. Chem. Soc. 107: 7077-83 (1985)

Cu(MePh2P)3Cl quenched by Norbornadiene at conc. 0.1-1 mol L–1
Solvent : Benzene, [CuCl] = 0.001 mol/L; [MePh2P] \f6=\fP 0.003 mol/L

kq = 8 x 107(L mol–1 s–1)

Mechanism: energy transfer
Experimental methods: steady state irradiation, quantum yield of a photoproduct
Comments: see Mech. [6]; other Cux(MePh2P)yClx species present

back...