Cr(3,4,7,8-Me4phen)33+

excited state quenched by Fe2+
Serpone, N.; Jamieson, M.A.; Henry, M.S.; Hoffman, M.Z.; Bolletta, F.; Maestri, M.
J. Am. Chem. Soc. 101: 2907-16 (1979)

Cr(3,4,7,8-Me4phen)33+ quenched by Fe2+
Solvent : H2O, 1 mol/L HCl, 25ºC

kq = 9.2 x 105(L mol–1 s–1)

Mechanism: reductive electron transfer
Experimental methods: steady state irradiation, luminescence
Lifetime in the absence of quencher, air saturated = 26 micro sec. ()

back...