Cr(bpy)33+

excited state quenched by trans-Co(cyclam)(H2O)(N3)2+
Endicott, J.F.; Ramasami, T.; Gaswick, D.C.; Tamilarasan, R.; Heeg, M.J.; Brubaker, G.R.; Pyke, S.C.
J. Am. Chem. Soc. 105: 5301-10 (1983)

Cr(bpy)33+ quenched by trans-Co(cyclam)(H2O)(N3)2+
Solvent : H2O, 1 mol/L NaClO4, 25ºC, pH 1

kq = 1.6 x 108(L mol–1 s–1)

Mechanism: energy transfer; reductive electron transfer
Experimental methods: conventional flash, absorption, single shot signal

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