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Cr(bpy)33+excited state quenched by cis-Co(en)2(H2O)Cl2+ | ![]() |
Cr(bpy)33+ quenched by cis-Co(en)2(H2O)Cl2+
Solvent : H2O, 0.1 mol/L H2SO4, 22ºC
kq = 2.2 x 107(L mol–1 s–1)
Mechanism: energy transfer
Experimental methods: steady state irradiation, luminescence
Lifetime in the absence of quencher, air saturated = 38 micro sec.
(laser flash, luminescence, multiple shot with signal averaging)