Al(phthalocyanine)Cl

excited state quenched by 1,4-Bis(N,N-dimethylamino)benzene
Ohno, T.; Kato, S.; Yamada, A.; Tanno, T.
J. Phys. Chem. 87: 775-81 (1983)

Al(phthalocyanine)Cl quenched by 1,4-Bis(N,N-dimethylamino)benzene
Solvent : DMA/H2O (2.3/1), ~28ºC

kq = 7.2 x 108(L mol–1 s–1)

Mechanism: reductive electron transfer
Experimental methods: laser flash, absorption, single shot signal
Electron transfer fraction of quenching = 0.84

Ohno, T.; Kato, S.; Yamada, A.; Tanno, T.
J. Phys. Chem. 87: 775-81 (1983)

Al(phthalocyanine)Cl quenched by 1,4-Bis(N,N-dimethylamino)benzene
Solvent : DMSO/H2O (4/1), ~28ºC

kq = 1.9 x 109(L mol–1 s–1)

Mechanism: reductive electron transfer
Experimental methods: laser flash, absorption, single shot signal
Electron transfer fraction of quenching = 0.85

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