'Quenching of Excited States of Metal Complexes

Al(phthalocyanine)Cl

excited state quenched by Fe(CN)₆^3–

Ohno, T.; Kato, S.; Yamada, A.; Tanno, T.
J. Phys. Chem. 87: 775-81 (1983)

Al(phthalocyanine)Cl quenched by Fe(CN)₆^3–
Solvent : DMA/H₂O (2.3/1), ~15ºC

k_q = 1.1 x 10⁷(L mol^–1 s^–1)

Mechanism: oxidative electron transfer
Experimental methods: laser flash, absorption, single shot signal
Electron transfer fraction of quenching = 0