Oxide radical ion Cerium(III) ion

Zehavi, D.; Rabani, J.
J. Phys. Chem. 75, 1738-1744 (1971)

Reaction: O·^- + Ce³⁺ ® Ce⁴⁺ + OH^-
Reference Reaction: O·^- + EtOH ®
Solvent: H₂O

pH range 2.6 to 2.9
k = 7.2 × 10⁸(L mol^-1 s^-1), k_reference = 1.2 × 10⁹(L mol^-1 s^-1), pH = 2.6, 2.9

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Relative value measured directly

C.k.; assuming k(·O^- + H₂O) = 1 × 10⁸ s^-1.