Fumarate ion Oxide radical ion

Cabelli, D.E.; Bielski, B.H.J.
Z. Naturforsch., B, Anorg. Chem., Org. Chem. 40B, 1731-1737 (1985)

Reaction: Fumarate ion + O·^- ® ^-O₂C^·C=CHCO₂^- + OH^-
Solvent: H₂O

k = 4 × 10⁷(L mol^-1 s^-1), T = 298K

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Derived from pH study

Product buildup kinetics at 280-400 nm at pH 4-10.5.