Oxide radical ion Ethanol

Buxton, G.V.; Greenstock, C.L.; Helman, W.P.; Ross, A.B.
J. Phys. Chem. Ref. Data 17, 513-886 (1988)

Reaction: O·^- + EtOH ® CH₃^·CHO^- + H₂O
Solvent: H₂O

k = 1.2 × 10⁹(L mol^-1 s^-1)

Data type: Selected or recommended value

Selected value.

Neta, P.; Schuler, R.H.
J. Phys. Chem. 79, 1-6 (1975)

Reaction: O·^- + EtOH ® CH₃^·CHO^- + H₂O
Reference Reaction: O·^- + ^-O₂CCH₂CH=CHCH₂CO₂^- ®
Solvent: H₂O

k = 1.2 × 10⁹(L mol^-1 s^-1), k_reference = 6.3 × 10⁸(L mol^-1 s^-1), pH = 14

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Relative value measured directly

Competition kinetics

Wander, R.; Gall, B.L.; Dorfman, L.M.
J. Phys. Chem. 74, 1819-1821 (1970)

Reaction: O·^- + EtOH ® CH₃^·CHO^- + H₂O
Solvent: H₂O

k = 1.1 × 10⁹(L mol^-1 s^-1), pH = 13.9

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Product buildup kinetics at 360 nm

Buxton, G.V.
Trans. Faraday Soc. 66, 1656-1660 (1970)

Reaction: O·^- + EtOH ® CH₃^·CHO^- + H₂O
Reference Reaction: ·OH + CO₃^2- ®
Solvent: H₂O

k = 1.0 × 10⁸(L mol^-1 s^-1), k_reference = 3.9 × 10⁸(L mol^-1 s^-1), pH = 11

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Relative value measured directly

Competition kinetics

Gall, B.L.; Dorfman, L.M.
J. Am. Chem. Soc. 91, 2199-2204 (1969)

Reaction: O·^- + EtOH ® CH₃^·CHO^- + H₂O
Reference Reaction: O·^- + O₂ ®
Solvent: H₂O

k/k_reference = 3.4 × 10^-1
k = 1.2 × 10⁹(L mol^-1 s^-1), k_reference = 3.6 × 10⁹(L mol^-1 s^-1), pH = 13

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Relative value measured directly

C.k.; cor. for ·OH.

Adams, G.E.; Boag, J.W.; Michael, B.D.
Trans. Faraday Soc. 61, 492-505 (1965)

Reaction: EtOH + O·^- ® CH₃^·CHO^- + H₂O
Reference Reaction: O·^- + O₂ ®
Solvent: H₂O

k/k_reference = 3.5 × 10^-1
k = 1.3 × 10⁹(L mol^-1 s^-1), k_reference = 3.6 × 10⁹(L mol^-1 s^-1), pH = >13

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Relative value measured directly

Competition kinetics