Oxide radical ion Dimethyl 2,2'-thiobisacetate

Maity, D.K.; Mohan, H.; Mittal, J.P.
J. Chem. Soc., Faraday Trans. 90, 703-709 (1994)

Reaction: O·^- + S(CH₂CO₂CH₃)₂ ® CH₃O₂C^·CHSCH₂CO₂CH₃
Solvent: H₂O

k = 3.0 × 10⁹(L mol^-1 s^-1), pH = 12.5, T = 298K

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Product buildup kinetics at 285 nm in N₂O-satd. soln. contg. 0.0013 mol L^-1 dimethyl thiodiglycolate.