18-Crown-6 Oxide radical ion

Ershov, B.G.; Seliverstov, A.F.; Sukhov, N.L.; Gordeev, A.V.
High Energy Chem. 21, 96-99 (1987)

Reaction: 18-Crown-6 + O·^- ®
Reference Reaction: O·^- + I^- ®
Solvent: H₂O

k = 5.4 × 10⁹(L mol^-1 s^-1), k_reference = 2.6 × 10⁹(L mol^-1 s^-1), pH = 13.6

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Relative value measured directly

C.k.; k = 9.2 × 10⁹ for KClO₄-18-crown-6 complex.