Crotonate ion Oxide radical ion

Neta, P.; Schuler, R.H.
J. Phys. Chem. 79, 1-6 (1975)

Reaction: CH₃CH=CHCO₂^- + O·^- ® ·CH₂CH=CHCO₂^- + OH^-
Solvent: H₂O

k = 9.0 × 10⁸(L mol^-1 s^-1), pH = 14

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Product buildup kinetics at 250 nm (allylic radical).