tert-Butylbenzene Oxide radical ion

Sehested, K.; Holcman, J.
Nukleonika 24, 941-950 (1979)

Reaction: C₆H₅C(CH₃)₃ + O·^- ® OH^- + C₆H₅C(CH₃)₂^·CH₂
Solvent: H₂O

k ~ 1 × 10⁹(L mol^-1 s^-1), pH = 13.6

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Product buildup kinetics in N₂O-satd. soln. contg. 0.6 mol L^-1 NaOH.