Oxide radical ion Benzyltributylammonium ion

Bobrowski, K.
J. Phys. Chem. 85, 382-388 (1981)

Reaction: O·^- + C₆H₅CH₂N⁺(C₄H₉)₃ ® C₆H₅^·CHN⁺(C₄H₉)₃ + OH^- + C₆H₅CH₂N⁺(C₄H₉)₂(^·C₄H₈)
Solvent: H₂O

k = 4.6 × 10⁸(L mol^-1 s^-1), pH = 14

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Product buildup kinetics at 305 nm in N₂O-satd. soln.; 25% H abstr. at benzyl and 75% at butyl.