Allyl alcohol Oxide radical ion

Neta, P.; Schuler, R.H.
J. Phys. Chem. 79, 1-6 (1975)

Reaction: H₂C=CHCH₂OH + O·^- ® H₂O + H₂C=CH^·CHO^-
Reference Reaction: O·^- + ^-O₂CCH₂CH=CHCH₂CO₂^- ®
Solvent: H₂O

k = 2.1 × 10⁹(L mol^-1 s^-1), k_reference = 6.3 × 10⁸(L mol^-1 s^-1), pH = 14

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Relative value measured directly

Competition kinetics with ethanol.

Simic, M.; Neta, P.; Hayon, E.
J. Phys. Chem. 77, 2662-2667 (1973)

Reaction: H₂C=CHCH₂OH + O·^- ® H₂O + H₂C=CH^·CHO^-
Solvent: H₂O

k = 2.9 × 10⁹(L mol^-1 s^-1), pH = 14

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Product buildup kinetics