Acrylonitrile Oxide radical ion

Buxton, G.V.; Ellis, P.G.; McKillop, T.F.W.
J. Chem. Soc., Faraday Trans. 1 75, 1050-1066 (1979)

Reaction: H₂C=CHCN + O·^- ® H abstr.
Reference Reaction: ·OH + CO₃^2- ®
Solvent: H₂O

k = 2.0 × 10⁹(L mol^-1 s^-1), k_reference = 3.9 × 10⁸(L mol^-1 s^-1), pH = 12.9

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Relative value measured directly

Competition kinetics in N₂O-satd. soln.