Aconitate ion Oxide radical ion

Neta, P.; Schuler, R.H.
J. Phys. Chem. 79, 1-6 (1975)

Reaction: ^-O₂CCH=C(CO₂^-)CH₂CO₂^- + O·^- ® OH^- + ^-O₂CCH=C(CO₂^-)^·CHCO₂^-
Solvent: H₂O

k ~ 1 × 10⁸(L mol^-1 s^-1), pH = 14

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Product buildup kinetics (allylic radical).