Acetylenedicarboxylate ion Oxide radical ion

Neta, P.; Schuler, R.H.
J. Phys. Chem. 79, 1-6 (1975)

Reaction: ^-O₂CCºCCO₂^- + O·^- ®
Reference Reaction: O·^- + ^-O₂CCH₂CH=CHCH₂CO₂^- ®
Solvent: H₂O

k = < 1 × 10⁷(L mol^-1 s^-1), k_reference = 6.3 × 10⁸(L mol^-1 s^-1), pH = 14

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Limiting value

C.k.; cor. for ·OH reactions; k_obs = 4 × 10⁷.