Acetonitrile Oxide radical ion

Neta, P.; Schuler, R.H.
J. Phys. Chem. 79, 1-6 (1975)

Reaction: CH₃CN + O·^- ® OH^- + ·CH₂CN
Reference Reaction: O·^- + ^-O₂CCH₂CH=CHCH₂CO₂^- ®
Solvent: H₂O

k = 2.1 × 10⁸(L mol^-1 s^-1), k_reference = 6.3 × 10⁸(L mol^-1 s^-1), pH = 14

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Relative value measured directly

Competition kinetics