Oxide radical ion Ammonia

Men'kin, V.B.; Makarov, I.E.; Pikaev, A.K.
High Energy Chem. 22, 333-336 (1988)

Reaction: O·^- + NH₃ ® ·NH₂ + OH^-
Reference Reaction: O·^- + O₂ ®
Solvent: H₂O

pH range 12 to 12.7
k = 3.0 × 10⁷(L mol^-1 s^-1), k_reference = 3.6 × 10⁹(L mol^-1 s^-1)

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Relative value measured directly

Competition kinetics

Mikhailova, T.L.; Ershov, B.G.
Proc. Fourth Working Meeting on Radiation Interaction, O. Brede and K.-H. Lubert (eds.), Cent. Inst. Isot. Radiat. Res., Leipzig, East Germany, 1987, p.577-81

Reaction: O·^- + NH₃ ® ·NH₂ + OH^-
Reference Reaction: O·^- + O₂ ®
Solvent: H₂O

k = 9 × 10⁶(L mol^-1 s^-1), k_reference = 3.6 × 10⁹(L mol^-1 s^-1), pH = >12

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Relative value measured directly

Competition kinetics