Oxide radical ion Chlorite ion

Eriksen, T.E.; Lind, J.; Merenyi, G.
J. Chem. Soc., Faraday Trans. 1 77, 2115-2123 (1981)

Reaction: O·^- + ClO₂^- ® ClO₂ + OH^-
Solvent: H₂O

k = 2.0 × 10⁸(L mol^-1 s^-1), pH = 14

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Product buildup kinetics at 360 nm

Buxton, G.V.; Subhani, M.S.
J. Chem. Soc., Faraday Trans. 1 68, 947-957 (1972)

Reaction: O·^- + ClO₂^- ® ClO₂ + OH^-
Reference Reaction: ·OH + CO₃^2- ®
Solvent: H₂O

k = 1.9 × 10⁸(L mol^-1 s^-1), k_reference = 3.9 × 10⁸(L mol^-1 s^-1), pH = 13

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Relative value measured directly

Competition kinetics