Hydroxyl [m-[N,N'-Bis(2-aminoethyl)]-13-methyl-13-nitro-1,4,8,11-tetraazacyclotetradecane-6,6-dimethanamine]dicopper(II) ion

Bernhardt, P.V.; Lawrance, G.A.; Sangster, D.F.
Polyhedron 10, 1373-1377 (1991)

Reaction: ·OH + [m-[N,N'-Bis(2-aminoethyl)]-13-methyl-13-nitro-1,4,8,11-tetraazacyclotetradecane-6,6-dimethanamine]dicopper(II) ion ® [m-[N,N'-Bis(2-aminoethyl)]-13-methyl-13-nitro-1,4,8,11-tetraazacyclotetradecane-6,6-dimethanamine]dicopper(II)(III) ion
Solvent: H₂O

k ~10¹⁰(L mol^-1 s^-1)

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Product buildup kinetics in N₂O-satd. soln.