Hydroxyl (R*,R*)-5,7,7,12,14,14-Hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-dienecopper(II) ion

Whitburn, K.D.; Laurence, G.S.
J. Chem. Soc., Dalton Trans., 334-337 (1979)

Reaction: ·OH + Cu(4,11-dieneN₄)²⁺ (R*,R*) ® H abstr.
Solvent: H₂O

pH range 1 to 5
k = 1.5 × 10¹⁰(L mol^-1 s^-1), T = 295K

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Relative value measured directly

Competition kinetics in H₂O₂ soln; obs. yield of oxidized complex; same transient formed by Cl₂^- reaction.