Octacopper(I) thionein Hydroxyl

Felix, K.; Lengfelder, E.; Hartmann, H.-J.; Weser, U.
Biochim. Biophys. Acta 1203, 104-108 (1993)

Reaction: Octacopper(I) thionein + ·OH ®
Reference Reaction: ·OH + SCN^- ®
Solvent: H₂O

k = 2.2 × 10¹¹(L mol^-1 s^-1), k_reference = 1.1 × 10¹⁰(L mol^-1 s^-1), pH = 7.0, T = 293K

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Relative value measured directly

Competition kinetics in N₂O-satd. soln.; thionein from yeast.