Hydroxyl trans-Dihydroxy(1,4,8,11-tetraazacyclotetradecane)chromium(III) ion

Monsted, O.; Nord, G.; Pagsberg, P.
Acta Chem. Scand., Ser. A 41, 104-109 (1987)

Reaction: ·OH + trans-Cr(cyclam)(OH)₂⁺ ® trans-Cr(cyclam)(OH)₂⁺/OH + H₂O
Solvent: H₂O

k = 2.0 × 10¹⁰(L mol^-1 s^-1), pH = 9.2, T = 295K

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Product buildup kinetics at 320 nm; N₂O-satd. soln.; p^·K_a = 3, 7.4