(2-Mercapto-2-methylpropionato-O,S)bis(ethylenediamine)chromium(III) ion Hydroxyl

Sullivan, J.C.; Deutsch, E.; Adams, G.E.; Gordon, S.; Mulac, W.A.; Schmidt, K.H.
Inorg. Chem. 15, 2864-2868 (1976)

Reaction: Cr(en)₂(SC(CH₃)₂CO₂)⁺ + ·OH ®
Solvent: H₂O

k = 8.2 × 10⁹(L mol^-1 s^-1), pH = 7

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Product buildup kinetics at 420, 410, 345 nm; two transients formed (oxid. at S and C).