Hydroxyl Pentacyano(nitrosyl)chromate(II) ion

Jezowska-Trzebiatowska, B.; Kalecinska, E.; Kalecinski, J.
Bull. Acad. Pol. Sci., Ser. Sci. Chim. 17, 225-231 (1969)

Reaction: ·OH + Cr(CN)₅NO^3- ®
Reference Reaction: ·OH + 4-Me₂NC₆H₄NO ®
Solvent: H₂O

k/k_reference = 6.3 × 10^-1
k = 7.9 × 10⁹(L mol^-1 s^-1), k_reference = 1.2 × 10¹⁰(L mol^-1 s^-1)

Experimental method: Gamma-radiolysis
Analytical method: vis-UV absorption
Data type: Relative value measured by steady state method

Competition kinetics; assumed k(·OH + CN^-) = 3.0 × 10⁹.