Hydroxyl Tris(2,2'-bipyridine)cobalt(III) ion

Maliyackel, A.C.; Waltz, W.L.; Lilie, J.; Woods, R.J.
Inorg. Chem. 29, 340-348 (1990)

Reaction: ·OH + Co(bpy)₃³⁺ ® Co(bpy)₃-OH³⁺
Solvent: H₂O

pH range 4.5 to 6.0
k = 2.7 × 10⁹(L mol^-1 s^-1), pH = 4.5, 6.0

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Product buildup kinetics at 415-425 nm in N₂O-satd. soln. contg. (9.8-25) × 10^-5 mol L^-1 Co(bpy)₃³⁺.