Hydroxyl Pentaammine(azido)cobalt(III) ion

Boucher, H.; Sargeson, A.M.; Sangster, D.F.; Sullivan, J.C.
Inorg. Chem. 20, 3719-3721 (1981)

Reaction: ·OH + Co(NH₃)₅(N₃)²⁺ ® [Co(NH₃)₅NNNOH]·²⁺
Reference Reaction: ·OH + SCN^- ®
Solvent: H₂O

k/k_reference = 1.7 × 10^-1
k = 1.8 × 10⁹(L mol^-1 s^-1), k_reference = 1.1 × 10¹⁰(L mol^-1 s^-1)

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Relative value measured directly

Competition kinetics