Hydroxyl Bis(ethylenediamine)dichlorocobalt(III) ion

Shinohara, N.; Lilie, J.
Inorg. Chem. 18, 434-438 (1979)

Reaction: ·OH + Co(en)₂Cl₂⁺ ®
Reference Reaction: ·OH + SCN^- ®
Solvent: H₂O

k/k_reference = 2.8 × 10^-2
k = 3.1 × 10⁸(L mol^-1 s^-1), k_reference = 1.1 × 10¹⁰(L mol^-1 s^-1), pH = 4.4

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Relative value measured directly

Competition kinetics

Shinohara, N.; Lilie, J.
Inorg. Chem. 18, 434-438 (1979)

Reaction: ·OH + Co(en)₂Cl₂⁺ ®
Reference Reaction: ·OH + C₆H₅CO₂^- ®
Solvent: H₂O

k/k_reference = 5.6 × 10^-2
k = 3.3 × 10⁸(L mol^-1 s^-1), k_reference = 5.9 × 10⁹(L mol^-1 s^-1), pH = 6.0

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Relative value measured directly

Competition kinetics

Shinohara, N.; Lilie, J.
Inorg. Chem. 18, 434-438 (1979)

Reaction: ·OH + Co(en)₂Cl₂⁺ ®
Solvent: H₂O

pH range 2.9 to 4.5
k ~3.0 × 10⁸(L mol^-1 s^-1)

Experimental method: Pulse radiolysis
Analytical method: conductivity
Data type: Absolute value measured directly

Product buildup kinetics (condy.)