Hydroxyl Tris(ethylenediamine)cobalt(III) ion

Shinohara, N.; Lilie, J.
Inorg. Chem. 18, 434-438 (1979)

Reaction: ·OH + Co(en)₃³⁺ ® H abstr.
Reference Reaction: ·OH + SCN^- ®
Solvent: H₂O

k/k_reference = 2.7 × 10^-2
k = 3.0 × 10⁸(L mol^-1 s^-1), k_reference = 1.1 × 10¹⁰(L mol^-1 s^-1), pH = 4.4

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Relative value measured directly

Competition kinetics in Ar-satd. soln.; pH effect studied.