Hydroxyl Iminodiacetatocobalt(II)

Srisankar, E.V.; Saha, N.C.; Mandal, P.C.; Bhattacharyya, S.N.
J. Chem. Soc., Dalton Trans., 1629-1634 (1984)

Reaction: ·OH + CoIDA ® CoIDA(OH)
Solvent: H₂O

k = 5.8 × 10⁸(L mol^-1 s^-1)

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Product buildup kinetics; 55% attack on metal ion, 45% attack on ligand; initial reaction suggested to be inner-sphere mechanism giving CoIDA(OH).