Nitrilotriacetatocobaltate(II) ion
Hydroxyl
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Nitrilotriacetatocobaltate(II) ion
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Bhattacharyya, S.N.; Srisankar, E.V.
J. Chem. Soc., Faraday Trans. 1 75, 2089-2099 (1979)
Reaction: CoNTA- + ·OH ®
Co[O2C·CHN(CH2CO2)2]- + H2O
Solvent: H2O
k = 1.0 × 109(L mol-1 s-1), pH = 7
Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Product buildup kinetics at 250 nm (e250 = 6400 L mol-1 cm-1). Discrepancy with other reported data. No recommendation.
Lati, J.; Meyerstein, D.
J. Chem. Soc., Dalton Trans., 1105-1118 (1978)
Reaction: ·OH + CoNTA- ®
Co[O2C·CHN(CH2CO2)2]- + H2O
Solvent: H2O
pH range 4 to 9
k = 5.0 × 109(L mol-1 s-1)
Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly
Product buildup kinetics. Discrepancy with other reported data. No recommendation.