Hydroxyl Chloride ion

Grigor'ev, A.E.; Makarov, I.E.; Pikaev, A.K.
High Energy Chem. 21, 99-102 (1987)

Reaction: ·OH + Cl^- ® ClOH^-
Solvent: H₂O

k = 3.0 × 10⁹(L mol^-1 s^-1)

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Product buildup kinetics at 340 nm in soln. contg. 1.2 mol L^-1 LiCl; k decreases as [Cl^-] increases 3.5-12.2 mol L^-1.

Jayson, G.G.; Parsons, B.J.; Swallow, A.J.
J. Chem. Soc., Faraday Trans. 1 69, 1597-1607 (1973)

Reaction: ·OH + Cl^- ® ClOH^-
Solvent: H₂O

Equilibrium constant = 0.70
k = 4.3 × 10⁹(L mol^-1 s^-1), pH ~2

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Decay kinetics at 240 nm as well as p.b.k. at 340 nm (Cl₂^-); k and K also given for ClOH^- + H⁺ Û Cl· + H₂O and Cl· + Cl^- Û Cl₂·^-.