Cyanamide Hydroxyl

Draganic, Z.D.; Draganic, I.G.; Jovanovic, S.V.
Radiat. Res. 75, 508-518 (1978)

Reaction: H₂NCN + ·OH ® H₂NC(OH)=^·N
Reference Reaction: ·OH + EtOH ®
Solvent: H₂O

k/k_reference = 4.6 × 10^-3
k = 8.7 × 10⁶(L mol^-1 s^-1), k_reference = 1.9 × 10⁹(L mol^-1 s^-1)

Experimental method: Gamma-radiolysis
Analytical method: chemical analysis
Data type: Relative value measured by steady state method

Competition kinetics; obs. G(CH₃CHO) in soln. contg. 0.1 mol L^-1 NH₂CN and 2.4 × 10^-4 mol L^-1 O₂; cor. for only 84% a-radicals yielding aldehyde.