Hydroxyl Carbonate radical ion

Holcman, J.; Bjergbakke, E.; Sehested, K.
Proc. Tihany Symp. Radiat. Chem. 6, 149-153 (1986)

Reaction: ·OH + CO₃·^- ®
Solvent: H₂O

pH range 8.5 to 11
k = 3.0 × 10⁹(L mol^-1 s^-1), pH = 8.5, 11.0

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Derived from fitting to complex mechanism

Computer simulation; obs. yield of CO₃^- in N₂O-satd. carbonate/bicarbonate soln.