Hydroxyl Carbon monoxide

Laming, F.P.; Buxton, G.; Wilmarth, W.K.
J. Phys. Chem. 73, 867-873 (1969)

Reaction: ·OH + CO ® ·CO₂H
Reference Reaction: ·OH + H₂O₂ ®
Solvent: H₂O

k/k_reference = 72
k = 2.0 × 10⁹(L mol^-1 s^-1), k_reference = 2.7 × 10⁷(L mol^-1 s^-1)

Experimental method: Photolysis
Analytical method: chemical analysis
Data type: Relative value measured by steady state method

Competition kinetics Discrepancy with other reported data. No recommendation.

Raef, Y.; Swallow, A.J.
Trans. Faraday Soc. 59, 1631-1640 (1963)

Reaction: ·OH + CO ® ·CO₂H
Reference Reaction: ·OH + Fe²⁺ ®
Solvent: H₂O

k/k_reference = 3.6
k = 1.6 × 10⁹(L mol^-1 s^-1), k_reference = 4.3 × 10⁸(L mol^-1 s^-1), pH ~1

Experimental method: Gamma-radiolysis
Analytical method: chemical analysis
Data type: Relative value measured by steady state method

Competition kinetics Discrepancy with other reported data. No recommendation.

Dainton, F.S.; Hardwick, T.J.
Trans. Faraday Soc. 53, 333-343 (1957)

Reaction: ·OH + CO ® ·CO₂H
Reference Reaction: ·OH + Fe²⁺ ®
Solvent: H₂O

k/k_reference = 3.8
k = 1.7 × 10⁹(L mol^-1 s^-1), k_reference = 4.3 × 10⁸(L mol^-1 s^-1), pH ~1

Experimental method: Fenton reaction
Analytical method: chemical analysis
Data type: Relative value measured by steady state method

Competition kinetics Discrepancy with other reported data. No recommendation.

Dainton, F.S.; Hardwick, T.J.
Trans. Faraday Soc. 53, 333-343 (1957)

Reaction: ·OH + CO ® ·CO₂H
Reference Reaction: ·OH + Fe²⁺ ®
Solvent: H₂O

k/k_reference = 2.4
k = 1.0 × 10⁹(L mol^-1 s^-1), k_reference = 4.3 × 10⁸(L mol^-1 s^-1), pH ~0.6

Experimental method: Fenton reaction
Analytical method: chemical analysis
Data type: Relative value measured by steady state method

Competition kinetics Discrepancy with other reported data. No recommendation.