Hydroxyl Bromate ion

Amichai, O.; Czapski, G.; Treinin, A.
Isr. J. Chem. 7, 351-359 (1969)

Reaction: ·OH + BrO₃^- ® BrO₃ + OH^-
Solvent: H₂O

pH range 12 to 13
k ~ 5 × 10⁶(L mol^-1 s^-1)

Experimental method: Flash photolysis
Analytical method: vis-UV absorption
Data type: Relative value measured directly

Competition kinetics; calcd. from pH dependence and effect on decay of O₃^- at 410 nm assuming k(·O^- + O₂) = 3.6 × 10⁹. Unrecommended value because of deficiencies in the method.