Hydroxyl Bromide ion

Zehavi, D.; Rabani, J.
J. Phys. Chem. 76, 312-319 (1972)

Reaction: ·OH + Br^- ® BrOH^-
Reference Reaction: ·OH + EtOH ®
Solvent: H₂O

k/k_reference = 5.8
k = 1.1 × 10¹⁰(L mol^-1 s^-1), k_reference = 1.9 × 10⁹(L mol^-1 s^-1), pH ~1

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Relative value measured directly

Competition kinetics; obs. at 360 nm (Br₂^-).