Hydrogen atom Tris(1,10-phenanthroline)iron(III) ion

Grodkowski, J.; Neta, P.; Schlesener, C.J.; Kochi, J.K.
J. Phys. Chem. 89, 4373-4378 (1985)

Reaction: H· + Fe(phen)₃³⁺ ® H⁺ + Fe(phen)₃²⁺
Solvent: H₂O

k = 4.0 × 10⁹(L mol^-1 s^-1), pH = <1

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Product buildup kinetics at 490 nm in soln. contg. tert-BuOH; fast step.

Janovsky, I.
Radiochem. Radioanal. Lett. 39, 337-341 (1979)

Reaction: H· + Fe(phen)₃³⁺ ® Fe(phen)₃²⁺ + H⁺
Solvent: H₂O

k = 5.0 × 10⁹(L mol^-1 s^-1), pH ~0

Experimental method: Pulse radiolysis
Analytical method: vis-UV absorption
Data type: Absolute value measured directly

Product buildup kinetics at 510 nm in soln. contg. 0.1 mol L^-1 tert-BuOH and 0.025 mol L^-1 H₂SO₄.